選購、購買X射線熒光光譜儀XRF分析儀器的技巧，注意事項和要領

不積跬步，無以至千里；不積小流，無以成江海

XRF 是一種原子發射光譜儀。在XRF中，來自X射線管主X射線束的輻射會使熒光X射線輻射表現出樣品中存在的元素能量分散的特性

其原理是 X 射線管通過產生入射 X 射線（初級 X 射線）來激發被測樣品。被激發樣品中的每種元素都會發出二次X射線（也稱為X射線熒光），不同元素所發出的二次X射線具有特定的能量特性或波長特性。檢測系統測量這些發射的二次 X 射線的能量和數量或波長。然后，儀器軟件將檢測系統采集到的信息轉化為樣品中各種元素的種類和含量。元素的原子被高能輻射激發，引起內部電子躍遷，同時發出具有一定特定波長的X射線。因此，只要測量熒光X射線的波長或能量，就可以知道元素的類型。這是熒光 X 射線定性分析的基礎。此外，熒光X射線的強度與相應元素的含量也有一定的關系。在此基礎上，可以進行元素的定量分析。當樣品用 X 射線照射時，樣品可以被激發以發出各種波長的 X 射線熒光。需要將混合后的X射線按波長（或能量）分離，分別測量不同波長（或能量）的X射線強度。對于定性和定量分析，為此使用的儀器稱為 X 熒光光譜儀。

國產與進口X射線熒光光譜儀技術對比與選購

進口品牌主要有以下幾家公司

Thermo Fisher 旗下的 Niton 手持設備和便攜式桌面設備

德國斯派克光譜

日本島津

英國牛津

還有日本的奧林巴斯。

國產品牌主要有

SKYRAY、ESI英飛思科學、HTEK、Cfan等

在技術上，經過近20年的深入積累和研發，國產XRF光譜儀與進口儀器的性能已經非常接近。這也是造成國外設備*逐步下降、終端價格大幅下降的主要原因。

2000年之前，進口XRF設備的價格通常在40萬到50萬之間。隨著國產XRF的逐步推進，進口設備的技術優勢也逐漸趕超。它必須進行大幅度的價格調整以適應中國市場。目前，進口設備的價格普遍定在20萬至40萬的水平。

具體到購買儀器和技術對比，客戶應注意以下幾點：

1.探測器的類型。不同類型的探測器，如比例計數盒、Si-pin、SDD和FSDD，其性能有很大差異，價格也有很大差異。

2、光管的選擇（功率、目標、端窗或側窗、玻璃或鈹窗、穩定性）

3、設備的測試重復性和穩定性非常重要。 X射線熒光光譜儀是基于X射線的元素定性定量分析技術。每個制造商根據不同的校準曲線對樣品進行量化。如果每次測試的偏差很大，無論聲稱多么精確的儀器，它都不起作用。這方面也是研究XRF儀器的重要依據。很多銷售人員會說XRF本身有不穩定性，這是事實，但如果偏差過大，也說明技術不夠好，測試起不到檢測的作用。測量穩定性和重復性是測量設備性能的關鍵指標。

通常我們可以對同一個標準樣品連續測量50次，通過檢測各元素RSD的相對標準偏差來驗證一個設備的性能。

如果光譜儀的硬件技術不夠好，儀器的穩定性是無法保證的。

4.設備的靈敏度是檢測下限。通常，很多廠家都吹噓儀器的檢測限可以達到1ppm，這其實是銷售人員的吹噓。客戶可根據手中的實際樣品進行跟蹤，測試設備檢測低含量樣品的性能。例如，它可以測試塑料中50ppm的Cl氯；銅合金中0.01%鎘Cd，0.005%鉛Pb，0.03%鋁Al；貴金屬金中0.01%鎘Cd；錫合金中0.005%鉻Cr；礦物質等中鎂、鋁、硅含量低。

5、為了儀器的長期穩定性，客戶可以每周對廠家提供的校準樣品進行測試。對于儀器長期穩定性優良的設備，同一校準樣品在長期跨度內的結果波動很小。

6. 軟件算法。由于X熒光光譜儀的主要干擾是基體效應和元素間增強吸收的作用，為了減少或消除這種干擾。軟件算法（包括光譜處理技術、強度擬合法、FP基本參數法、α理論系數法、經驗系數法等）尤為重要。

7. 售后和技術支持。這通常是國產儀器的優勢所在，而良好而持續的售后服務也是國產儀器*不斷提升的重要原因之一。

ESI擁有一整套自主研發的X熒光光譜儀技術，與市場上大多數設備相比具有明顯的技術優勢。該儀器在測試穩定性和靈敏度方面可以達到進口儀器的水平。

近年來，隨著XRF國產化的不斷深入，市場上的品牌良莠不齊。很多廠商只是在打價格戰，降低了研發投入和售后質量

如果客戶在采購XRF儀器時遇到困難，建議直接寄樣品給廠家進行檢測。或請廠家到現場PK，一目了然地見證產品的測試性能。不要被銷售人員片面的言論所迷惑。

如果您有任何測試需求，ESI提供免費元素測試服務

Technical comparison and purchase of domestic and imported X-ray fluorescence spectrometers

If a worker wants to do his job well, he must first sharpen his tools.

XRF is an atomic emission spectrometer. In XRF, the radiation from the main X-ray beam of the X-ray tube will cause the fluorescent X-ray radiation to show the characteristics of the dispersed energy of the elements present in the sample

The principle is that the X-ray tube excites the sample under test by generating incident X-rays (primary X-rays). Each element in the excited sample emits secondary X-rays (also called X-ray fluorescence), and the secondary X-rays emitted by different elements have specific energy characteristics or wavelength characteristics. The detection system measures the energy and quantity or wavelength of these secondary X-rays emitted. Then, the instrument software converts the information collected by the detection system into the types and contents of various elements in the sample. The atoms of the element are excited by high-energy radiation to cause the transition of the inner electrons, and at the same time emit X-rays with a certain specific wavelength. Therefore, as long as the wavelength or energy of the fluorescent X-rays is measured, the type of the element can be known. This is fluorescence The basis of X-ray qualitative analysis. In addition, the intensity of fluorescent X-rays has a certain relationship with the content of corresponding elements. Based on this, quantitative analysis of elements can be carried out. When the sample is irradiated with X-rays, the sample can be excited to fluoresce X-rays of various wavelengths. It is necessary to separate the mixed X-rays by wavelength (or energy) and measure the intensity of X-rays of different wavelengths (or energy) respectively. For qualitative and quantitative analysis, the instrument used for this is called X fluorescence spectrometer.

Technical comparison and purchase of domestic and imported X-ray fluorescence spectrometers

Imported brands mainly include the following companies

Niton handhelds and portable desktop devices under Thermo Fisher

Spectro Germany

Shimadzu

Oxford, UK

And Olympus of Japan.

Domestic brands mainly include

SKYRAY, ESI, HTEK, Cfan, etc.

Technically, with the in-depth accumulation and research and development in the last 20 years, the performance of domestic XRF spectrometers and imported instruments have been very close. This is also the main reason for the gradual decline in the market share of foreign equipment and the sharp decline in terminal prices.

Before 2000, imported high-end XRF equipment was usually at a price of 400,000 to 500,000. With the gradual progress of domestic XRF, the technical advantages of imported equipment have gradually caught up and surpassed. It has to make substantial price adjustments to adapt to the Chinese market. At present, the price of imported equipment has generally been set at the level of 200,000 to 400,000.

This is a convenient change in market pricing. From a purely technical perspective, the current advantages of imported XRF fluorescence spectrometers are mainly in software core algorithms and brand premiums. In terms of hardware technology, except for some sub-sectors, such as wavelength dispersive X fluorescence spectrometer, secondary target X fluorescence spectrometer, etc., imported equipment has no advantages at all.

Specific to the purchase of instruments and technical comparison, customers should pay attention to the following points:

1. The types of detectors. Different types of detectors, such as proportional counting box, Si-pin, SDD and FSDD, have very different performances, and their prices are also very different.

2. Selection of light pipe (power, target, end window or side window, glass or beryllium window, stability)

3. The test repeatability and stability of the equipment are very important. X-ray fluorescence spectrometer is based on the element qualitative and quantitative analysis technology of X-ray. Each manufacturer quantifies the samples according to different calibration curves. If the deviation of each test is large, No matter how precise an instrument is claimed, it will not work. This aspect is also an important basis for investigating XRF instruments. Many sales staff will say that XRF itself has instability, which is a fact, but if the deviation is too far, it also means that the technology is not good enough, and the test will not play the role of detection. Measurement stability and repeatability is a key indicator for measuring equipment performance.

Usually we can measure the same standard sample 50 times continuously, and examine the relative standard deviation of the RSD of each element to verify the performance of a device.

If the hardware technology of the spectrometer is not good enough, the stability of the instrument cannot be guaranteed.

4. The sensitivity of the equipment is the lower limit of detection. Usually, many manufacturers boast that the detection limit of the instrument can reach 1ppm, which is actually the boast of the salesperson. Customers can follow up the actual samples in their hands to test the performance of the equipment in detecting low-content samples. For example, it can test 50ppm Cl chlorine in plastic; 0.01% cadmium Cd in copper alloy, 0.005% lead Pb, 0.03% aluminum Al; 0.01% cadmium Cd in precious metal gold; 0.005% chromium Cr in tin alloy ; Low content of magnesium, aluminum and silicon in minerals, etc.

5. For the long-term stability of the instrument, customers can test the calibration samples provided by the manufacturer every week. For equipment with excellent long-term stability of the instrument, the fluctuation of the result of the same calibration sample in the long-term span is very small.

6. Software algorithm. Since the main interference of the X fluorescence spectrometer is the matrix effect and the effect of enhancing the absorption between elements, in order to reduce or eliminate this interference. Software algorithms (including spectrum processing technology, intensity fitting method, FP basic parameter method, alpha theoretical coefficient method, empirical coefficient method, etc.) are particularly important.

7. After-sales and technical support. This is usually the advantage of domestically-made instruments, and good and continuous after-sales service is also one of the important reasons for the increasing market share of domestically-made instruments.

ESI has a complete set of self-developed X fluorescence spectrometer technology, which has obvious technical advantages with most equipment on the market. The instrument can reach the level of imported instruments in terms of test stability and sensitivity.

In recent years, as the localization of XRF continues to deepen, brands on the market are mixed with good and bad. Many manufacturers are simply fighting price wars, which reduces R&D investment and after-sales quality.

If customers encounter difficulties in the procurement of XRF instruments, it is recommended to send samples directly to the manufacturer for testing. Or ask the manufacturer to go to the site to PK and witness the test performance of the product at a glance. Don't be fooled by the one-sided words of the salesperson.

If you have any testing requirements, ESI provides free element testing services, please consult for details